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I note that resistive
differences are not principally assigned to differences in the number of
conduction electrons, but rather in their 'mobility'.
In this respect, it's helpful to tweak the iconoclasts who take pleasure
in reminding us that electrons do not travel down a wire at near the speed
of light, (though energy usually does),
about a statistical feature of electron motion, so to speak.
Notwithstanding their strictures about the snail's pace of DRIFT
velocity - it is quite permissible to visualize electron velocity as
several million meters per second (electric field or no...)
The model for resistance in metals is the probability that an electron
will collide with an ionic barrier.
Ref 1 holds up nickel vs. nichrome
as an example of two materials with very similar numbers of conduction
electrons, but widely different resistivity (20:1)