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Hi Ludwik:
We don't have to work at the atomic level, to exhibit the
principle of non-linear response functions for intense
radiation. Just realize that at high intensities the transmitted
(and, hence, reflected) waves in a medium are proportional
not just to E, the electric intensity, but also to E^2, etc.
But if E carries a single frequency, then E^2 carries the
doubled frequency, etc.