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I think the static voltage misconception is discussed in Aaron's book on
teaching introductory physics. I recall that the problem is reversed, ie,
that students don't think a "battery" or "power supply" will supply the
charge (voltage) of static machines, like Van de Graaff's.
Regarding the humidity leaking charge explanation: What is the accepted
mechanism? I know my electrostatics demos don't work when the
humidity is high, so I am guilty of saying that the charge leaks
off....Karl