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[Phys-L] the historical determination of absolute zero



This is from a popular science book by the physicist George Gamow:

   “If we heat the liquid the wild dance of tiny particles suspended in
   it becomes more violent; with cooling the intensity of the motion
   noticeably subsides. This leads no doubt that we are actually
   watching here the effect of the hidden thermal motion of matter, and
   that what we usually call temperature is nothing else but a
   measurement of the degree of molecular agitation. *By studying the
   dependence of Brownian motion on temperature, it was found that at
   the temperature of -273˚ C *or -459˚ F, thermal agitation of matter
   completely ceases, and all its molecules come to rest.”

Leaving aside the sense of observations leaving 'no doubt' about a theoretical interpretation (rather counter to the idea of theory always being underdetermined by observation) I was very surprised to read that absolute zero had been found from studies of Brownian motion rather than, say, change in volume/pressure of a gas or some other method.

I would have thought 'well, I never knew that', but I am not sure how reliable Gamow is. (Elsewhere in the same book he has neutrons decaying to protons AND protons decaying to neutrons <https://science-education-research.com/glossary/proton-decays-into-a-neutron/>, in both cases emitting neutrinos and electrons/positrons, which to my mind could have solved our power supply issues - if it had been correct.) Is Gamow right about Brownian motion? I thought Brownian motion was only well understood after Einstein in 1905, well after absolute zero was estimated?

Keith

--

“The main point to realise is that all knowledge presents itself within a conceptual framework adapted to account for previous experience and that any such frame may prove too narrow to comprehend new experiences" <https://science-education-research.com/commonplace/>


Dr. Keith S. Taber
https://science-education-research.com <https://science-education-research.com>

Emeritus Professor of Science Education
University of Cambridge
http://www.educ.cam.ac.uk/staff/taber.html

Senior Member
Homerton College, Cambridge

Editor-in-Chief, Royal Society of Chemistry Book Series:
/RSC Advances in Chemistry Education/ <https://science-education-research.com/advances-in-chemistry-education/>
<https://science-education-research.com/advances-in-chemistry-education/>